4-Chloro-N-(4-methylbenzoyl)benzenesulfonamide
نویسندگان
چکیده
In the title compound, C(14)H(12)ClNO(3)S, the conformation of the N-H bond in the C-SO(2)-NH-C(O) segment is anti to the C=O bond. The mol-ecule is twisted at the S atom with a torsion angle of 69.0 (2)°. The dihedral angle between the sulfonyl benzene ring and the -SO(2)-NH-C-O segment is 77.2 (1)° and that between the sulfonyl and the benzoyl benzene rings is 89.5 (1)°. In the structure, mol-ecules are linked into chains via N-H⋯O hydrogen bonds, forming inversion dimers.
منابع مشابه
4-Chloro-N-(2-methylbenzoyl)benzenesulfonamide
In the title compound, C(14)H(12)ClNO(3)S, the conformation of the N-H bond in the C-SO(2)-NH-C(O) segment is anti to the C=O bond. The two aromatic rings are tilted relative to each other by 57.7 (1)°. In the crystal, mol-ecules are linked by pairs of N-H⋯O(S) hydrogen bonds, forming centrosymmetric dimers.
متن کامل4-Chloro-N-(3-methylbenzoyl)benzenesulfonamide monohydrate
In the title compound, C(14)H(12)ClNO(3)S·H(2)O, the dihedral angle between the sulfonyl and benzoyl benzene rings is 84.4 (2)°. In the crystal, every water mol-ecule forms four hydrogen bonds with three different mol-ecules of 4-chloro-N-(3-methyl-benzo-yl)benzene-sulfonamide. One of the water H atoms forms a bifurcated hydrogen bond with both the sulfonyl and the carbonyl O atoms of the same ...
متن کامل2-Chloro-N-(4-methylbenzoyl)benzenesulfonamide
In the title compound, C(14)H(12)ClNO(3)S, the conformation of the N-H bond in the C-SO(2)-NH-C(O) segment is anti to the C=O bond. The dihedral angle between the sulfonyl benzene ring and the -SO(2)-NH-C-O segment is 89.4 (1)° and that between the sulfonyl and benzoyl benzene rings is 89.1 (2)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O hydrogen bonds.
متن کامل2-Chloro-N-(2-methylbenzoyl)benzenesulfonamide
In the title compound, C(14)H(12)ClNO(3)S, the N-H bond is anti-periplanar to the C=O bond. The dihedral angle between the two aromatic rings is 78.7 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O(S) hydrogen bonds.
متن کامل2-Chloro-N-(3-methylbenzoyl)benzenesulfonamide
In the title compound, C(14)H(12)ClNO(3)S, the N-H bond is in an anti-periplanar conformation to the C=O bond. The dihedral angle between the two aromatic rings is 74.7 (1)°. The crystal structure features inversion-related dimers linked by N-H⋯O hydrogen bonds.
متن کامل